Hi, John,
I know the conventional wisdom is that mfg's list max psi ratings as half of the tested blow-off pressure, but even if this was true many years ago, it may not be true any longer. I'd be hesitant to go so far above max psi, since there doesn't seem to be much benefit to doing so, based on BQ's more recent tests of rolling resistance variation with tire pressure, which showed rolling resistance increasing with higher psi, above a certain point. With my Pasela 700x32's at 95psi front and back, I've never had problems either with pinch flats or with feeling like the tires are flexing too much in turns or when standing up. So going with high pressure seems like it doesn't really "solve a problem." And to the extent that you are taking on some amount of risk, your stoker might be happier for you not to do so. Hard, extended braking on a downhill can certainly heat a rim enough to increase the effective psi on a tire, so if the tire is already potentially somewhat overstressed taking downhill corners at 40mph with 300+ pounds of weight on it, then overpressuring it might actually get you closer to the blowoff point than is comfortable.
FWIW, I asked Jan Heine about using the Grand Bois Cypres (700x30) on a tandem and he discouraged that idea. Which is a little too bad, because on one ride where I hadn't noticed that I had run the Pasela down to the threads, the tire finally wore through and we got a flat and fortunately we were carrying a Cypres as a spare. It felt notably plushier than the Pasela, even on the back of the tandem.
Nick