Hi Suman,
You can do this by configuring electrodes and enabling the transport module.
For an introduction on working with the transport module and electrodes see Tutorial 10 in the manual.
e.g. define an electrode with addelectrode command with a given rectangle (see help for this command in the manual or console: ?addelectrode).
you will need at least 2 electrodes, and designate on of them as the ground electrode, e.g. first one: desginateground 0.
you can then set a potential drop, e.g. setpotential 1, for 1 V.
Alternatively, if you just want a constant current density then use the setcurrentdensity (transport module still required).
Regards,
Serban