Collin,
You managed to highlight how my brief generalization is not that air-tight. Regular glass has broadband NIR absorption as well and when you go to 10mm thickness the tables have turned. I added low-iron for comparison showing how little that absorbs in NIR.
Numbers from Optics:
Record, Tvis, Tsol, Absolute difference
3mm (larger difference for acrylic)
Clear_3.dat, 0.899, 0.834, -0.065
Acrylic_3.dat, 0.923, 0.849, -0.074
Starphire_3.vta, 0.914, 0.902, -0.012
10mm (larger difference for clear glass)
Clear_10.dat, 0.860, 0.685, -0.175
Acrylic_10.dat, 0.915, 0.803, -0.112
Starphire_10.vta, 0.907, 0.872, -0.035