Hi Dan,
The “posterior” statistic it is the log of the posterior probability for each state in the chain, P(X_i | D), for parameters X in step i given data D.
The “likelihood” statistic is the likelihood of the data for each state in the chain, P(D | X_i). So if you average this statistic over the MCMC chain you get the average probability of the data, over the parameter space *weighted by the posterior* (since the MCMC chain is a random sample from the posterior).
In contrast the marginal likelihood, P(D), is the average probability of the data over the parameter space *weighted by the prior*. So you need to arrive at it using a different technique, like path sampling.
Cheers
Alexei