This seems to work. It's a little tricky to be sure you're at the start of a sentence so I'd advice cycling through the matches rather than doing a global replace.
Search pattern: (?:^|\. +)[a-z]
Replace pattern: \L\0
Use with grep and case sensitive turned on. The search pattern finds either the start of a line ^ or an escaped period followed by one or more spaces, wrapped in (?: ) so they don't define a sub-pattern. Followed by the lowercase character. The replacement uses \U to make the replacement uppercase. And we replace the whole pattern so we don't lose the period.
Hope this helps,
[fletcher]
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