Dear SSY,
we've done a hefty dose of such simulations using diffusion.h. Now, what usually makes it stiff (not divergent, stiffness was a better description of our case) was: 1. often, parameters ended up not well chosen, i.e. in parameter studies we had inputs orders of magnitude off the physical ones, diffusion.h was very sensitive to that; 2. certain grid resolutions. This means that e.g. you can have a stiff solver with octree at maxlevel N, but at N-1 or N+1 (if you can afford it) it's not stiff.
I know this is very empirical, but usually, after making sure all params are physical, convergence was in reach.
kindly
Voitek A.
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