Under Android 11 are my screenshots under /storage/emulated/0/Pictures/Screenshots, and not under the Digital Camera directory. Maybe you've chosen that destination yourself, for a screenshotting flow? But then OTOH wouldn't you need to monitor that directory for changes.
Check, using a file manager, that the specified path "/storage/emulated/0/DCIM/Screenshots/.pending-...-Screenshot-...` actually exists, because the error message indicated that it doesn't.
For the apparently too long directory name, try whether it helps to specify it differently: Rather then as interactive non-fx choice, try to specify it as function (tapping the struck-out "fx" in the path specification) "{storage()}/Android/media/com.whatsapp/WhatsApp/..." (with double quotes) or storage(Android/media/com.whatsapp/WhatsApp/...) (without quotes an curly braces).
If that doesn't help, I'd try a shell function to copy those files instead, assuming that those files serve as source of a copy operation which is likely when backupping them. The command to copy them by shell command is "cp source destination", with source and destination replaced against the actual files and paths. For source, you may want to use a wildcard for files, as in {storage()}/dirs/*
An command line switch -R for also copying subdirectories exists.