Please file the FITSFixedWarning report with astropy -- that FITS file looks fine to me.
As for finding your standard stars: on that web page, it only gives coordinates to 1 second -- 60 pixels in your image! Not surprising it's off by 30 pixels.
Comparing against the USNO-B1 coordinates, your field seems to be well solved:
http://nova.astrometry.net/user_images/415849#redgreenOne other thing to watch out for is that not all FITS tools understand the SIP polynomial distortion corrections we produce. They're small for your image (< 1 pixel, I think); you can turn off SIP with "solve-field --no-tweak [...]"
By the way, here it is in SDSS:
http://skyserver.sdss3.org/dr8/en/tools/explore/obj.asp?ra=190.5852&dec=-0.6745And with those coordinates I get the observed position:
> wcs-rd2xy -w SA104_R.new -r 190.58506428 -d -0.67456481
RA,Dec (190.5850642800, -0.6745648100) -> pixel (1136.1351972232, 1144.0002793254)
cheers,
--dustin