You would design this circuit so that you're always running off the batteries and the PV panels are charging the batteries. Just like in a data center. It's not much different than what I built for the solar powered wifi ap, just higher amperage. You can buy solar charge controllers off the shelf for this application. The circuits are fairly simple.
Not sure why you'd use two electric motors to drive one axle. Seems like over complexity and you'd basically be wasting the differential in the axle. I'd mount one motor to drive the prop shaft for the rear axle directly. Then you could always have the option of converting it to 4wd with either another motor driving the front axle or a beefier motor driving a center differential driving both axles. You could get multiple gear ratios that way so your two speed motor could give you multiple drive gears in lots of configurations (2wd locked, 2wd slip, 4wd locked, 4wd slip, front or rear digs, etc)
Also, you should talk to the guys at RechargeCar. They have several products but their big claim to fame is modding ICE vehicles with electric motors. They are based here in Nashville and I'm hoping they present at the Real Bar Camp coming up. I can make an introduction if you have interest.