The Toucams can all be modified to perform long exposures (the
"SC" (Steve Chambers) mod) and there are loads of guides on the net to
do this. The reason why these webcams are so good is the Sony CCD that
is used - these are excellent. However, if you are really handy with a
soldering iron/making circuit boards, then you can take it much
further than this and replace the CCD sensor with the icx414/icx424
like the Atiks). Greg Beeke details the mod here:
http://cosmicshed.blogspot.com/2007/11/icx414-sc4-webcam-modifications.html
And the icx424 replacement is on Steve's website at
http://www.pmdo.com
Another alternative is to replace the colour chip with a more
sensitive b/w chip (the ICX098BL) which doesn't gain you any chip
size, but gives you a better response. You could also design a cooling
system for the toucams too - again several guides out there.
There's also the Meade DSI range - the DSI III has a large chip - but
the price takes it into the realms of "proper" ccd cameras.
The Imaging Source cameras are good (I have one) - though they are
touted more as planetary cameras since they have quite small pixels,
the "AS" versions do long-exposures, and the more expensive ones do
have reasonably sized chips.
The Atik range have some good cameras and give very good results
(though are less like webcams, since they even come with cooling and
an ST4 guider socket :) The Atik-16ic really is a very good camera
for the money.
Other options include something like an integrating video camera like
the Watec - though to record the results you'll need a video capture
card (or some way of converting the video out signal to a PC friendly
one).
Cheers,
GC