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QUESTION: Detonation Velocity

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dizum

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Mar 24, 2005, 12:54:28 PM3/24/05
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I had small argument with my friend about detonation velocities. I said that
there is no (or almost no) explosives with detonation velocity above 10,000
m/s.
He was mentioning "Trauzl test" - explosion in the lead block. Never heard
of that.
So I have a question. Is there any explosive with detonation velocity above
10,000 m/s?
Would somebody provide information or link?
Thank you.


donald j haarmann

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Mar 24, 2005, 10:26:41 PM3/24/05
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"dizum" <di...@dizum.com


--------
TNN with velocity of 9 600 m/sec is going to be hard to beat!

Herr Trauzel's lead block test has little to do with det. vel. It is — one method of measuring
the power of an explosive.


---------
Oscar Guttmann
The Manufacture of Explosives
Macmillan and Co. New York 1895

CHAPTER XXII
APPARATUS FOR THE EXAMINATION OF EXPLOSIVES
III POWER GAUGES

D. TRAUZL'S LEAD BLOCK TEST.

In 1877 Captain Dr. Beckerhinn had already tried detonating, explosives in a
perfectly uniform medium in order to obtain an idea both of the force of an
explosion, and the shape of the cavity produced by it. For this purpose be
compressed regularly piled paper sheets to a packet of 6 inches in height, in
such a way that they formed a homogeneous medium, and drilled cavities in it to
receive the charge and fuse. Beckerhinn also effected explosions in lead, plastic
clay, and hard and soft wood, but obtained less favourable results with these
materials.

Later Mr. Isidore Trauzl resuscitated this ideal and by using a suitable form of
lead cylinders, and indicating an easy manner of charging, was able to place at
the disposal of experimenters the very practical apparatus which is now
generally used.

Lead blocks 200 millimeters (about 8 inches) diameter and of the same height
are cast in an iron mould, the construction of which is shown in Figs. 315 and
316. Along the axis there is a cylindrical cavity 20 millimeters (about 3/4 inch) in
diameter and 110 millimeters (about 4 3/8 inches) deep. The mould is made
easily, and by overturning the bottom part it falls out from the iron core piece for
forming the central hole. Exactly 20 grammes of the explosive are placed in the
cavity, a detonator and fuse are inserted, the bore filled with dry sand, and the
charge fired. Theoretically, a spherical cavity ought to be produced by the
explosion, but as some gases escape through the channel left by, the fuse, and
as the resistance of the tamping is less than that of the lead, the actual cavity
produced is pear-shaped (shown in Fig. 317 by the dotted line). The volume of
this cavity, which is measured by filling it with water from a graduated vessel, is a
measure of the strength of the explosive. As the hardness of lead varies, and is
increased by re-melting, it is advisable to keep in stock a number of lead blocks
cast at one melting, and when trying an explosive to make a trial with the
standard one it is to be compared with-usually kieselguhr dynamite containing 75
per cent. of nitro-glycerin. If this be done, very reliable results will be obtained.

Although this apparatus and Guttmann's [Power Gauge /djh/] give very
valuable assistance in judging explosives, the reader is warned against relying
upon them entirely for drawing absolute conclusions as to, the suitability of
various explosives for any specific purpose. The circumstances attending
blasting operations in rock vary so much, and the requirements are so various in
different places, that a decisive opinion can only be formed by a trial extending
over several weeks, made in precisely equal workings, and after careful
calculation and 'consideration of all the advantages and disadvantages.


----------
MEDINA has a lead block value of 210% (TNT = 100).


--
donald j haarmann
----------------------------
An explosion may be defined as a loud noise
accompanied by the sudden going away of
things from the places where they were before.
Joseph Needham


dizum

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Mar 25, 2005, 5:11:52 PM3/25/05
to
Thank you Donald, your answers on this NG are always 100% excellent.

Now I have more questions:
*What is TNN? (TNN with velocity of 9 600 m/sec is going to be hard to
beat!)
*What is MEDINA?

Thank you very much.


donald j haarmann

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Mar 25, 2005, 6:40:52 PM3/25/05
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"dizum" <di...@dizum.com> wrote in message news:I001e.15458$C47....@newssvr14.news.prodigy.com...


--------------
Trinitronapthalene (TNN; Naphtite) Me thinks it is a liquid. Will check.

Methylenedinitramine (MEDINA)


--------
Lead block more :—


Arthur Marshall
Explosives
2nd ed. Volume II.
Properties and Tests
J. & A. Churchill London 1917

CHAPTER XXX
POWER AND VIOLENCE OF EXPLOSION

[Figures are the same as in Colver. /djh/]

Trauzl's lead block test affords a ready means of ascertaining the approximate
relative strength of explosives. It consists in firing a charge of the explosive in a
hole in a block of lead and measuring the size of the cavity formed. At the Fifth
International Congress of Applied Chemistry, held at Berlin in 1903, standard
conditions were laid down for carrying out the test :

" The lead cylinder is 200 mm. in height and 200 mm. in diameter. In its axis is a
hole 125 mm. deep and 25 min. in diameter to take the charge. The purest
refined soft lead should be used, and for comparative trials the cylinders should
all be from one melting. The sketch (Fig. 92) shows a convenient form of mould
for casting the blocks. In order to pre-heat the mould, a red-hot ring is placed
round it.

" The Process. The blocks should be allowed to stand after casting sufficiently
long to attain a uniform temperature of 15o to 20o. Ten g. of the explosive are
weighed out and wrapped in a piece of tin-foil, of 80 to 100 g. per sq. metre, of
the dimensions shown at the bottom of Fig. 92, so as to form a cartridge of 25
mm. diameter. An electric detonator containing a charge of 2 g. is inserted into
the centre of the cartridge. The cartridge is carefully pressed home with a
wooden rod keeping the wires central. For tamping, sharp dry quartz sand is
used, which passes through a sieve of 144 meshes per sq. cm. (30 meshes to
the inch), the wire being 0-35 mm. thick. The sand is run in until the hole is full,
and the excess is removed. The charge is then fired electrically. Afterwards the
lead block is inverted and any residue is removed with a brush. The quantity of
water is then ascertained that is required exactly to fill the cavity. This, less the
original volume of the hole, gives a measure of the power of the explosive. [The
enlargement caused by a detonator alone under the same conditions is also
deducted sometimes.— A.M.]

Interpretation of the Results. (1) Lead block tests can only claim to give
satisfactory comparative results when they are made with the same class of high
explosive. If there be great differences in the speed with which the pressure
develops, the results are no longer comparable.

" (2) Statements as to the strength of explosives should always be based on
at least three determinations.

" (3) The reliability of the test is affected considerably : (a) By the uniformity of
the temperature of the lead at the time of the test. The standard temperature is
15o to 20o C. (b) by the uniformity of the tamping ; (c) by the uniformity of the
test."

The lead block test has the advantage that it imitates fairly closely conditions in a
bore-hole, only unfortunately the charge has to be small. The warning against
using the test for the comparison of explosives with different velocities of
detonation appears to be unnecessarily emphatic, for both Kast [Spreng- und
Zündstoffe, p. 1030.] and Dautriche [Compt. rend., 144, 1907, p. 1032; S.S.,
1907, p. 313.3 Ang.,, 1911, p. 2234.] have found that the results are unaffected
by considerable variations in the density to which explosives are compressed,
although this has a very great influence on the velocity of detonation. In the case
of non-detonating explosives, such as black powder, the test fails, however, as
the tamping is blown Out before the full pressure is developed, or the gases
escape through it, unless a more resistant tamping material be used, such as
Portland cement. Probably the results are affected more by the temperature of
explosion, the lead on the interior surface being eroded by the hot gases. For
this reason aluminium explosives, which produce very high temperatures, give
unduly high results in the lead block. If the lead blocks were weighed before and
after the test, and the results corrected for the quantity of metal eroded away, it
is possible that the figures would be more satisfactory.

Neumann gives the following as typical results with the Trauzl test:
[Ang., 1911, p. 2234]

Nitro-glycerine 540 c.c.
Blasting gelatine 530 c.c.
Gelignite 420 c.c. (65 NIG, 25 NaNO3, 8 W.M.)
Gesteins-Wstfalit 380 c.c. (Ammonium nitrate exp.)
Picric acid 315 c.c.
Trinitro-toluene 290 c.c.
Safety gelatine dynamites 200-300 c.c.

Some of the modern safety explosives have been so far, diluted to meet the
requirements of the gallery tests, however, that they enlarge the cavity less than
200 c.c.

In France the Trauzl test is carried out somewhat differently. [Vennin et
Chesneau, p. 101 ; P. et S,, vol. 15, p. 227.] The dimensions of the lead block
are the same. The explosive is placed carefully in the hole, the height that it
occupies is measured, and the density is calculated. A detonator containing 1.5
g. fulminate is passed through a bark cork 5 mm. thick which fits easily into the
hole in the lead. The detonator should project into the explosive at least 25 mm.
The explosive is tamped with dry sand which passes a mesh of 0.35 mm. and
weighs about 1.300 g. per litre. This is poured without agitation on to the cork.
Tests are carried out to ascertain the charge that produces the same
enlargement as 15 g. of picric acid fired under the same conditions. It is not
necessary to continue the tests until the exact equivalent has been found as the
enlargement V is related to the weight of charge by the formula V = KC (sup) 1.4.
The following are the co-efficients thus obtained, picric acid being taken as 100 :

Picric acid 100
Blasting gelatin 155
Dynamite No. 1 102
Grisoutine roche 100
" couche 75
Grisounaphthalite roche, N1b 103
" couche, N1a 81
salpétrée, N4, 78
Favier N1c 111
Na Cheddite 0, No. 5 86
Cheddite 0, No. 2 82
Mining powder, strong 52
" " ordinary 48

Black powder, or other non-detonating explosive, is mixed first with a suitable
high explosive.

The Trauzl test in trials at D'Anzin in 1897 gave results in good agreement with
those obtained in the mine. [Vermin et Chesneau, p. 109.]

Explosive
Theoretical
Potential
Q
Power by
Bomb
Test
Trauzl
Test
Industrial
Result
Blasting gelatine
100
100
100
100
Dynamite No. 1
73
67
66
67
Grisoutine (70 per cent.)
41
72
66
69
Grisoutine B Ablon (88 per cent.)
37
60
50
53
Blasting powder (ordinary)
43
28
31
31

Kling and Florentin have found that the results are not affected appreciably by
reducing the temperature of the explosive to —80o or even to –190o. [P. et S.,
vol. xvii., 1913, p. 151]

Tests are also carried out in France in the earth in a meadow where the soil is as
uniform as possible and has not been disturbed for many years. [Vennin et
Chesnealu, p. 104: P. et S, vol, XV. p. 229.] Holes are drilled 2 metres apart, 1
metre deep, and 29 mm. in diameter. These are charged with 150 to 200 g. of
the explosive and fired with No. 7 detonators. There should be no projection of
earth. The diameter D and the height H of the cavity formed are measured and
the capacity is calculated from the formula V= 1/6 (pi) D (sup) 2 H. From this the
volume of the original drill hole is deducted and the difference is the measure of
the power of the explosive. The tests are carried out in comparison with a
standard explosive of the same type. The results do not always place the
explosives in the same order as the Trauzl test or as trials carried out in mines
under actual working conditions, as is shown by the following figures obtained at
D'Euville in 1910:

Explosive
Power by
Bomb Test
Earth
Test
Trauzl
Test
Industrial
Result
Picric acid
100
100
100
100
Favier N1c
90
102
104
111
Cheddite 02
67
115
86
90

Blocks of concrete 500 mm. in diameter and height are also used some-
Concrete test. times with charges of 5 to 10 g. of explosive. The results obtained
are much the same as those yielded by the Trauzl test, but are not so readily
expressed in figures. [Vennin et Chesneau, p. 105.]

Another appliance, that is used to determine the comparative strcngth Ballistic of
explosives, is the ballistic pendulum. …….


--
donald j haarmann
---------------------------
"It is essential that persons having explosive
substances under their charge should never
lose sight of the conviction that, preventive
measures should always be prescribed
on the hypothesis of an explosion."


dizum

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Mar 29, 2005, 12:00:01 PM3/29/05
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"donald j haarmann" <donald-...@worldnet.att.net> wrote in
message....snipped

Donald, thank you very much, your knowledge and answers are excellent.
You have a nice day sir.
dd


Short Fuse

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Apr 1, 2005, 3:38:25 AM4/1/05
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Just something I had laying around...
Explosive -

Blasting Agent
Detonation

Velocity

M/Sec.
Specific Gravity G/CM3
Lead Block

cm3 10g

---------

%TNT

300 cm3=100%
Source

Black powder
400
1.60
10%
2700 B268

Silver acetylide
1880
--
44%
2700 A79

Tetramminennickle (II) nitrate
2400
--
53%
2700 C463

Ammonium nitrate
2800
1.3
75%
2700 B267

Ammonium perchlorate
3000
1.2
100% by BM
2700 B267

Cheddite [KClO3/DNT/Castor oil /MNN 79/15/5/1]
3000
1.3
88-92%
2700 B269

Cheddite On o2 60bisM
3000
--
89%
2700 C157

Minélite C
3125
1.84
74% of PA
2700 M134

Minélite B
3180
1.90
72% of PA
2700 M134

Ammonium chlorate
3300
--
85%
2700 C185

Minélite A [Potassium chlorate]
3355
1.92
74% of PA
2700 M134

Dynammon
3380
--
83%
2700 A289

Ammonium/perchlorate
3400
--
46% of PA
2700 P150

Ammonal A
3450
--
110%
2700 A289

Silver(Di) acetylide/ Silver nitrate (Complex)
3460
3.96
48%
2700 A80

Guanidine nitrate
3700
--
10%
2700 G151

Wasamon W
3700
1.1
97%
2700 W6

Wasamon F
4200
1.05
105%
2700 W6

Gesteins-Koronite T2
4300
1.46
93%
Davis

Dynamite, Low Velocity Picatinny Arsenal
4397
0.9
92% by BM
********

Perkoronit B
4400
1.52
110%
Davis

Nitrostarch (12.12% N)
4480
0.9
108%
2700 B283

HMTD (Hexamethylenetriperoxide diamine)
4500
1.57
110%
K&M

Aldorfit(e) (Alldorfit)
4500
1.05
125%
2700 A123

Wasagel
4800
1.45
123%
2700 W6

Hexanitroethane (HNE)
4950
0.91
82%
K&M

Perkoronit A
5000
1.58
113%
Davis

Mercury fulminate
5000
4.0
37-50%
2700 F220

Gesteins-Koronite T1
5000
1.57
97%
Davis

Fivolite (2,2,5,5-Tetramethylolcyclopentanol pentanitrate)
5060
0.75
160%
2700 F40

Amatoxol [AN 80/Toxol (TNT 70/TNX 30) 20%]
5100
--
118% of PA
2700 A165

HMTD (Hexamethylene-triperoxide-diamine, HMTPDA)
5100
1.1
60%
2700 B277

Lead styphnate
5200
2.9
43%
K&M

Sulfone [2,4,6,2',4',6'-Heanitrodipenyl-]
5210
--
107% PA
2700 D1480

Isosorbitol dinitrate
5300
1.08
104%
K&M

Triaminoguanidine nitrate (TAGN)
5300
0.95
117%
K&M

Amatol 80/20
5300
1.6
126%
2799 B267

Nitrostarch (12.8% N)
5300
0.9
127%
2700 B283

Lead azide
5300
4.6
37%
K&M

Hexamminenickel (II) perchlorate
5300
1.36
91%
2700 A281

Ammonal T
5400
1.60
162%
2700 A291

Baronal
5450
2.32
90% by BM
2700 B22

Amatol 60/40
5500
1.61
128% by BM
2700 A159

Cyanuric triazide
5500
1.02
138%
K&M

Cupric azide
5500
--
38%
2700 A532

Cupric azide
5500
--
38%
2700 A532

Cyanuric triazide
5600
1.15
140%
2700 C590

Ethyl nitrate
5800
1.1
140%
K&M

Minol II
5900
1.68
165%
2700 M138

Baratol 90/10
5900
1.65
98%
2700 B19

B268

Telsit
6000
1.55
129%
2700 B288

Dinitrobenzene (DNB)
6100
1.50
85%
2700 B47

PLX (liquid)
6165
1.14?
127%
2700 P315

Nitrostarch (13.35-13.45% N)
6190
0.9
145%
2700 B283

Amatol 40/60
6200
1.6
128% by BM
2700 B267

Amatol 50/50
6200
1.6
128% by BM
2700 B267

Ethylenediamine dinritrate (Ph-Satz, EDD)
6270
1.33
125%
2700 E236

Nitromethane (NM; NMe)
6290
1.138
400/133%
K&M

Methyl nitrate
6300
1.217
203%
K&M

Tridite 60/40
6300
1.6
92%
2700 B291

Ethritol trinitrate
6440
1.48
138%
K&M

Trimethylolpropane trinitrate [1,1,1-] (EMMET)
6440
--
138%
2700 T373

Amatol 45/55
6470
--
112%
2700 A159

Ethane azidonitrate
6550
1.34
150%
2700 E143

Ethanol azidonitrate (2-Triazo-1-ethanol nitrate)
6550
1.34
150%
2700 E177

Aziodohydroxytetrazole
6550
1.34
161-70%
2700 B268

Tritional/D2 95/5
6560
1.68
123% by BM
2700 B295

Dynamite, Medium Velocity Picatinny Arsenal
6600
1.1
122% by BM
********

DEGN (Diethylenglycol dinitrate)
6600
1.38
137%
K&M

Trinitroxylene (TNX, Xylyl)
6600
1.51
93%
2700 B294

Tridite 70/30 (Shellite)
6600
1.6
95%
2700 B291

Trinitro-m-cresol [2,4,6-]
6620
1.52
85%
2700 C557

Glycerol chloride dinitrate
6750
1.54
158%
K&M

Tritonal 80/20 [TNT/Aluminium]
6770
1.76
153%
2700 B295

Ethylenediamine dinritrate (Ph-Satz, EDD)
6800
1.53
117%
K&M

DEGN (Diethylenglycol dinitrate)
6800
1.38
134-58%
2700 B271

DBX (Depth Bomb Explosive)
6800
1.65
146% by BM
2700 D19

Dintriophenoxyethylnitrate
6800
1.58
93%
K&M

Trinitroanisole (Methyl picrate, TNAns)
6800
1.57
98%
K&M

Trinitrocersol [2,4,6-]
6850
1.62
95%
K&M

Trinitrocresol (TNCrs, Cresylite)
6850
1.62
99%
2700 B292

Trinitrochlorobenzene (Picryl chloride, TNCB)
6855
1.71
103%
2700 C250

TNT
6900
1.60
100%
K&M

Hexamite
6900
1.72
116%
2700 B277

HBX-3
6917
1.81
111% by BM
********

TNTF (2,4,6-Trinitrobenzotrifluoride)
6919
1.718
114%
2700 T298

Tridite 90/10
7000
1.6
102%
2700 B291

Novit 60/40 [TNT/HNDPhA]
7000
1.5
105%
2700 B284

Hexanitrodiphenysulfide [2,4,6,2',4',6'-]
7000
1.65
107%
K&M

Type 98 Explosive 60/40 [TNAns/HNDPha]
7000
1.5
108%
2700 B295

Trinitrobenzene (TNB)
7000
1.64
111%
2700 B48

Diethylolamine trinitrate
7000
1.55
131% of PA
2700 D1242

Cheddite Sevranite no2
7000
1.55
142% CUP PA
2700 C159

Pentral 50/50 15% Al
7000
1.62
150%
2700 P137

Mannitol Hexanitrate
7000
1.5
172%
2700 M13

Trinitroaniline [2,4,6-] (TNA, Picramide)
7000
1.5
98%
2700 A410

Tetramethylolcyclopentanone tetranitrate
7040
1.55
129%
K&M

Dinitrodimethyloxamide (MNO, DNDMO)
7050
1.5
116%
2700 D1360

PIPE
7075
1.37
106%
2700 P303

B287

Trimonite
7080
1.60
94%
2700/B292

Diazodinitrophenol (DDNP; Dinol; Diazol; DADNPh)
7100
1.63
105-110%
2700B271

B59

Dinitrodimethyloxamide
7100
1.48
120%
K&M

Hexanitrodiphenylamine (HNDPhA, HNDP)
7150
1.67
115%
2700 D1436

Guanidine perchlorate
7150
1.67
133%
2700 G152

Ammonium picrate (Explosive D)
7150
1.6
93%
K&M

Hexanitrodiphenyl oxide [2,4,6,2',4',6'-]
7180
1.65
124%
K&M

Novit
7200
1.68
105%
2700 N172

Pentral 60/40 15% Al
7200
1.68
163%
2700 P137

Trinitrochlorobenzene (Picryl chloride, TNCB)
7200
1.74
315/105%
K&M

Hexanitrodiphenylamine [2,4,6,2',4',6'-] (Hexite, Hexil, Hexl)
7200
1.60
325/108%
K&M

HBX-1 [High Blast Explosive]
7224
1.69
133% by BM
2700 H24

Ethylenedinitrate [Diammonium] (AEDNA)
7231
1.35
69.5% of PA
2700 E243

Tacot [Tetranitrodibenzo-1,3a,4,6a-tetrazapentalene]
7250
1.64
96% by BM
2700 D1184

Butanetriol trinitrate [1,2,3-]
7270
1.60
140% by BM
2700 B281

Trinitroaniline
7300
1.72
103%
K&M

Picirc acid
7300
1.767
105%
K&M

Nitrobenzene [1,3,5-Tri-]
7300
1.71
108%
K&M

Cyclotrimethylene trinitrosamine (R-Salt)
7300
1.42
122-6%
2700 B271

C 630

EDNAFIVE [50/50 EDNA/Fivonite]
7300
1.57
129%
2700 E245

Nitrocellulose (N13.2-13.4)
7300
1.3
136-47%
2700 B282

EGDN Nitroglycol, Ethyleneglycol dinitrate
7300
1.48
206%
K&M

Nitroglycol
7300
1.48
207%
K&M

106 (1,9-Dinitroxy-2,4,6,8-tetranitro-2,4,6,8,- Tetraazanonane)
7305
1.265
164%
2700 D1396

Trifluorethylnitrammine [2,4,6-Trinitrophenyl-B,B,B-] (TFEt; Tetryl)
7335
1.690
144%
2700 T167

Ednatol 55/45
7340
1.63
119%
2700 B274

Ednatol 55/45
7340
1.63
120%
2700 E245

Ethanol nitrate 2-(2',4',6'-Trinitro-N-nitranilino) ("Pentryl")
7340
1.65
125%
2700 A426

Pentryl (Trinitronitranilinoethanol nitrate)
7340
1.65
130%
2700 B286

Tetrytol 70/30
7350
1.61
120%
2700 T165

B290

Nitrobenzene [1,3,5-Triazido-2,4,6-tri-] (TATNB)
7350
1.805
157%
K&M

Nitrobenzene [1,3,5-Triamino-2,4,6-] (TATB)
7350
1.80
58%
K&M

RIPE
7390
1.37
118% by BM
2700 R174

Hexanitrodiphenylamine (HNDPhA, HNDP)
7400
1.64
102-8%
2700 B278

HEX-1 (High Energy Explosive)
7400
1.69
133% by BM
2700 B277

Trinitroethyl)-urea [1,3-Di(2,2,2-] (BTNEU)
7400
--
153%
2700 D1254

Pentral 70/30 15% Al
7400
1.65
166%
2700 P137

Dipentaerythritol hexanitrate (DPEHN)
7410
1.59
144%
2700 D1412

Nitro-N-methyl-hydroxyacetamide nitrate [N-]
7420
1.50
132% by BM
2700 B283

Methylhydroxyacetamide nitrate [N-Nitro-N-]
7420
1.5
133% by BM
2700 M107

Nitromethylglycolamine nitrate (Hyman)
7420
1.5
133% by BM
2700 B283

Sixolite (Tetramethylolcyclohexanone tetranitrate)
7430
1.58
135%
2700 B288

Pentral 50/50
7450
1.55
120%
2700 P137

Ednatol 60/40
7475
1.62
117%
2700 B274

Cyclotol 40/60
7485
1.68
123% by BM
2700 B270

Torpex
7495
1.81
164%
********

Nitrobenzene [1,3- Diamino-2,4,6-Tri] (DATNB; DATE)
7500
1.65
175/58%
********

Aminomethane perchlorate
7540
1.68
160%
2700 A227

Ethylenedinitramine (EDNA; Haleite; Halite)
7570
1.49
122%
2700 D1137

E238

Ethylenedinitramine (EDNA; Haleite; Halite)
7570
1.65
137%
K&M

Tetryl (Trinitro-2,4,6-phenylmethylnitramine)
7570
1.73
137%
K&M

Fivonite (FV) (2,2,5,5-Tetramethylolcyclopentanone tetranitrate)
7592
1.57
129%
2700 F41

Trinitrophenoxethyl nitrate
7600
1.65
117%
K&M

Pentral 60/40
7600
1.56
123%
2700 P137

Borotorpex [RDX 46, TNT 44, Boron 10%]
7600
1.74
129% by BM
2700 B257

Nitroglycerine (NG)
7600
1.59
173%
K&M

Nitroisobutyglycerol trinitrate (NIBTN)
7600
1.68
180%
K&M

Composition C-3
7625
1.60
117%
********

Tetranitroaniline (TeNA)
7630
1.6
140%
2700 A412

Trinitroanisole [2,4,6-] (Methyl picrate, TNAns)
7640
--
112%
2700 A450

Torpex-2
7660
1.80
166%
2700 B291

Dinitroethyleneurea (DNEU)
7690
1.6
120%
2700 E292s

Penastit 93/7 w/ 20% aluminium
7700
1.68
161%
2700 B285

Penastit 96.5/3.5 w/ 20% aluminium
7700
1.67
176%
2700 B285

PEP-3
7780
1.47
118% by BM
2700 P137

Pentral 70/30
7800
1.58
121%
2700 P137

Bonit No. 2 [TNT/RDX 30/70]
7800
1.78
140&
2700 B242

NENO (Dinitrodi(b--nitroxyethyl oxamide)
7800
1.62
145%
2700 B272

Dioxyethylnitramine dinitrate (DINA)
7800
1.6
160%
2700 B271

Composition B
7840
1.69
130%
2700 C479

NENO (N,N'-Dinitro-N,N' bis (2-hydroxyethyl)-oxamide Dintrate)
7860
1.65
143%
2700 D1244

Nitroisobutylglycerol trinitate (NIBGTN)
7860
1.64
145/55%
2700 N113

HTA-3 [HMX 49, TNT 29, Al 22%]
7866
1.90
120% by BM
2700 H176

106 (1,9-Dinitroxy-2,4,6,8-tetranitro-2,4,6,8,- Tetraazanonane)
7895
1.35
155% by BM
2700 B273

Cyclotol 60/40
7900
1.72
130% by BM
2700 B270

Cyclotol 65/35
7975
1.72
133% by BM
2700 C479

B270

PTX-1
8000
1.68
132% by BM
2700 B287

Pentasit 93/7
8000
1.56
140%
2700 B285

Nitrogen tetroxide/Nitrobenzene 69.8/30.2
8000
--
168%
2700 P4

Blasting gelatin [NG 92/NC 8%]
8000
1.55
194%
2700 B268

Cyclotol 75/25
8035
1.70
137% by BM
2700 C479

B 270

Cyclotol 70/30
8060
1.73
145%
2700 C479

B270

PTX-2
8065
1.70
145% by BM
2700 B287

Nitroguanidine (NQ; Picrite)
8200
--
102%
K&M

Mannitol hexanitrate (MHN)
8260
1.73
170%
K&M

PETN (Pentaerythritol tetranitrate)
8400
1.7
174%
K&M

Pentrinit 80/20
8400
1.72
179%
2700 B286

Methylenedinitramine (MEDINA)
8500
1.68
188-210%
2700 B280

M51

Hydrazine nitrate
8690
1.60
136%
K&M

Cyclonite
8750
1.76
160%
K&M

Octogen (HMX)
9100
1.9
160%
K&M

rba...@hotmail.com

unread,
Apr 3, 2005, 11:57:46 PM4/3/05
to
>Octogen (HMX)
>9100
> 1.9
>160%
> K&M


Mate....... you had a short fuse .........but slow burning!<g>
How about HNIW which is the current interest in the military due to
being more powerful than HMX( higher VOD and detonation pressures.)

Short Fuse

unread,
Apr 4, 2005, 5:16:10 AM4/4/05
to
HNIWor CL-20. 2,4,6,8,10,12-hexanitrohexaazaisowurtzitane... Say that after
half a dozen Bundys. About 20% more powerful than HMX. Did some research
(read quick search) and still no VOD. Your reply was the first I had heard
of it. How about Octanitrocubane? 25% more powerful than HMX.


rba...@hotmail.com

unread,
Apr 4, 2005, 11:35:06 AM4/4/05
to
VOD of CL-20?
You can find a basic explosive property description from the US
patent 5693794 tittled Caged Polynitramine Compound.
Regarding Octanitrocubane? aw,, forget it....it is just of an
academic and theoritical importance.nothing more!

Hrondo

unread,
Apr 8, 2005, 3:59:09 AM4/8/05
to
> --------
> TNN with velocity of 9 600 m/sec is going to be hard to beat!
>
> Herr Trauzel's lead block test has little to do with det. vel. It is ? one method of measuring

> the power of an explosive.
> ----------
> MEDINA has a lead block value of 210% (TNT = 100).


Surely upon surely the VOD of TNN is not 9600m/s, I know where this
come from but I would think its an error. Maybe they forgot to covvert
it from 9600ft/sec (2926m/s) which sounds about right for its density
(0.9g/cm3).

Does anything beat MEDINA in the trauzel test? I know it can be beat
by other tests but that figure is very high.

Boomer

unread,
Apr 8, 2005, 6:42:31 PM4/8/05
to
HNIW 9,400 m / S, d = 2.1 g /cm^3, Pcj = 420 kbar

--
Boomer

Want to talk chemistry ? The Reef Chemistry Forum
http://www.reefcentral.com/vbulletin/index.php

WCW...@Chartermi.Net
Former US Army Bomb Technician (EOD)
Member; IABTI, NATEODA, WEODF, ISEE & IPS

If You See Me Running You Better Catch-Up


"Short Fuse" <shor...@mail.com> wrote in message
news:425105dd$0$5393$afc3...@news.optusnet.com.au...
: HNIWor CL-20. 2,4,6,8,10,12-hexanitrohexaazaisowurtzitane... Say that after

:
:


hyt

unread,
Apr 9, 2005, 9:23:39 AM4/9/05
to

Boomer wrote:
> HNIW 9,400 m / S, d = 2.1 g /cm^3, Pcj = 420 kbar
>
> --
> Boomer

Whats the reference for that Boomer?

Boomer

unread,
Apr 9, 2005, 5:51:49 PM4/9/05
to
There are many on the net and in my explosive books. I took the one from : Chemistry of
Energetic Materials, Ch 5, Polycyclic Amine Chemistry, page 99


Here is just one of them on the net.

http://www.gr.admin.ch/internet/armasuisse/de/home/unsere/wissenschaft/explosivstoffe.Par.0007.DownloadFile.tmp/C2103_Mathieu.pdf.Also just search on this NG we have many posts on it. You can also calculate it within 1-2 % by using Stine Equations. I have posted them here in the past. Don should have somealso.--BoomerWant to talk chemistry ? The Reef Chemistry Forumhttp://www.reefcentral.com/vbulletin/index.p...@nospamChartermi.NetFormer US Army Bomb Technician (EOD)Member; IABTI, NATEODA, WEODF, ISEE & IPSIf You See Me Running You Better Catch-Up"hyt" <hy...@hotmail.com> wrote in messagenews:1113053019.3...@z14g2000cwz.googlegroups.com...:: Boomer wrote:: > HNIW 9,400 m / S, d = 2.1 g /cm^3, Pcj = 420 kbar: >: > --: > Boomer:::: Whats the reference for that Boomer?:

donald j haarmann

unread,
Apr 9, 2005, 7:45:49 PM4/9/05
to
"Hrondo" <hron...@yahoo.com


-----
Yup. The density appears low ... here is the quote from PATR-2700. vol. 8, N 13

... and its deton vel is from 6470m/sec at d 1.60 to 9600m/sec at d 0.9 g/cc
both at 180o (Ref 30) [Why 180o !]

30 - L. Médard, MP 34, 397 (1952) & CA 49 4293h (1955)


Density of 1.60 would put it in good company : -


Nitromethane/toulene 9300m/sec @ 1.6g/cc
Pentanitrophenyl azide 9210 @ 1.76
Glycoluril 9150 @ 2.01
Sorguyl 9150 @ 1.95
Octahydryo-1,3,5,7-tetranitro-1,3,5,7-Tetrazocine 9110 @ 1.89
Octogen 9100 @ 1.9


--
donald j haarmann
---------------------------------
The explosion removed the windows,
the door and most of the chimney.

It was the sort of thing you expected in
the Street of Alchemists. The neighbours
preferred explosions, which were at least
identifiable and soon over. They were better
than the smells, which crept up on you.
Terry Pratchett


donald j haarmann

unread,
Apr 10, 2005, 10:10:42 AM4/10/05
to
<rba...@hotmail.com

> VOD of CL-20?
> You can find a basic explosive property description from the US
> patent 5693794 tittled Caged Polynitramine Compound.
> Regarding Octanitrocubane? aw,, forget it...

>it is just of an
> academic and theoritical importance.nothing more!
>


----------
Yup - Yet the strange attraction to numbers again.

PAX-29 (77% CL-20) 2.0023 g/cc Dv 8.77 km/s
LX-14 (95.5% HMX) 1.835 g/cc 8.80 km/s
PAX-11 (94% CL-20) 1.951 9.52 km/s

Exp En ergy @ V/VO=6.5 E sub 6.5 kJ/cc
Total Mechanical Energy
E sub tot (Kj/cc)

PAX-29 11.04 14.61
LX-14 8.59 10.27
PAX-11 10.29 14.81
&c

stkolev

unread,
Apr 10, 2005, 11:29:31 AM4/10/05
to
" Glycoluril 9150 @ 2.01
Sorguyl 9150 @ 1.95 "

Same thing (TNGU)



" Octahydryo-1,3,5,7-tetranitro-1,3,5,7-Tetrazocine 9110 @ 1.89
Octogen 9100 @ 1.9 "

Same thing (HMX)

hyt

unread,
Apr 11, 2005, 12:03:12 AM4/11/05
to
Thanks Boomer.

I had a look at the stine equation, I would be inteested in seeing the
original article on it. Is it possible for your to email it to me?

I ran some common HE's through it and recieved:

STINE
explosive= calculated (measured)
TNT= 6848m/s (6930m/s)
PETN= 8374m/s (8260m/s)
TETRYL= 7620m/s (7850m/s)
NM= 6529m/s (6350m/s)

Not bad.

Are you familiar with the equation of Kamlet & Jacobs? requires the
same known values, but also incorporates gas volume and mass which are
easily calculated. Have you tried comparing the Stine values to these?
I plan on doing a few comparisons, but it does take time.

KAMLET & JACOBS
explosive= calculated (measured)
TNT= 6970m/s (6930m/s)
ETN= 8040m/s (????)

Richard Harding

unread,
Apr 11, 2005, 5:26:51 PM4/11/05
to
"donald j haarmann" <donald-...@worldnet.att.net> wrote in message news:<NOZ5e.548913$w62.4...@bgtnsc05-news.ops.worldnet.att.net>...
...SNIP...

> Nitromethane/toulene 9300m/sec @ 1.6g/cc

...SNIP.....
>
>
> --
> donald j haarmann


Wasn't it Tetranitromethan + Toluene?

Tetranitromethan is much more vile stuff than Nitromethane.

Richard

Boomer

unread,
Apr 11, 2005, 5:27:06 PM4/11/05
to
Maybe later this summer. I don't have a copier right now. I got it from Stine after a few
of us found issues with it in Zukas & Walters book; Explosive Effects and Applications,
where it is explained incorrectly, so you get the wrong answer..

Yes I have played with the others, I just found this soooooo much easier for me.

If you are in the USA you can get it from a public library by request, if you have the
original title. Did I post it long ago ?

--
Boomer

Want to talk chemistry ? The Reef Chemistry Forum

http://www.reefcentral.com/vbulletin/index.php

WCW...@nospamChartermi.Net


Former US Army Bomb Technician (EOD)

hyt

unread,
Apr 11, 2005, 11:01:36 PM4/11/05
to

Perhaps I should have searched the group for Kamlet/Jacobs, since you
have brought it up a number of times before. I agree that Stine (Stein?
you have given both) is a lot faster to do. I also found mention that
stine gave a comparison table to ther formulas, it would be interesting
to see.

Im not in the US, however a journal reference should be fine, as long
as its not too obscure. Please post the full reference.

For others, heres the Journal references to the other VOD formulas.

M. J. Kamlet & S. J. Jacobs, Journal of Chemical Physics. 48, 23-35
(1968)
M. J. Kamlet & H. Hurwitz, Journal of Chemical Physics. 48, 3685-3692
(1968)
L. R. Rothstein & R. Peterson, Propellants-explosives-pyrotechnics. 4,
56-60 (1979)
L. R. Rothstein & R. Peterson, Propellants-explosives-pyrotechnics. 6,
91-93 (1981)

donald j haarmann

unread,
Apr 12, 2005, 10:02:52 AM4/12/05
to

"Richard Harding"

> "donald j haarmann"

> ...SNIP...
>
> > Nitromethane/toulene 9300m/sec @ 1.6g/cc
>
> ...SNIP.....
> >
> >
> > --
> > donald j haarmann
>
>
> Wasn't it Tetranitromethan + Toluene?
>
> Tetranitromethan is much more vile stuff than Nitromethane.
>
> Richard

Yes teta- brevis esse aboro, obscurus fio.

--
donald j haarmann - independently dubious


Boomer

unread,
Apr 12, 2005, 5:43:04 PM4/12/05
to
Stine, as in

J.R.Stine, LANL, Group M-1 MS-C920. Los Alamos, NM 87545

On Predicting Properties of Explosives - Detonation Velocity

Journal of Energetic Materials vol. 8, 041-073 (1990), Published in 1990 by Dowdsen,
Brodman & Devine, Inc.


"I also found mention that
stine gave a comparison table to ther formulas"

Yes, 24 explosives, comparing Sine to two other formulas but not what you think :-), There
are extended versions of Urizar equations from the 1940 when he was at LANL > You can find
these in ;

LLNL Explosive Properties Handbook-Properties of Chemical Explosives and Explosive
Stimulants, Jan 1985

I have had the ISEE selling this book for years for years, I brought it to there
"Blaster's Library" , it is $30 USA. If you have the money and want to "deep-six" yourself
there is Charlie's book

Numerical Modeling of Explosives and Propellants, Charles L. Mader

http://isee.org/

Maybe you may be interested in my old friends website, the famous Ray Rogers of LANL. He
was director of the famous DX Division for 40 years and taught Mader, his best friend

http://home.att.net/~rnrogers/

--
Boomer

Want to talk chemistry ? The Reef Chemistry Forum
http://www.reefcentral.com/vbulletin/index.php

WCW...@nospamChartermi.Net
Former US Army Bomb Technician (EOD)
Member; IABTI, NATEODA, WEODF, ISEE & IPS

If You See Me Running You Better Catch-Up


"hyt" <hy...@hotmail.com> wrote in message
news:1113274896....@g14g2000cwa.googlegroups.com...
:
: Perhaps I should have searched the group for Kamlet/Jacobs, since you

:


dizum

unread,
Apr 12, 2005, 7:43:38 PM4/12/05
to
Thank you everybody for all information.


Richard Harding

unread,
Apr 13, 2005, 4:51:40 PM4/13/05
to

>donald j haarmann

>Yes teta- brevis esse aboro, obscurus fio.

ego te absolvo

Rolf Prümmer

unread,
Apr 24, 2005, 11:26:42 AM4/24/05
to

"dizum" <di...@dizum.com> schrieb im Newsbeitrag
news:o9D0e.15076$C47....@newssvr14.news.prodigy.com...
>The fastest DV is 9.400 m/s. The explosive is CL20, named
>after the place where it was developed: China Lake.


Short Fuse

unread,
May 5, 2005, 2:17:45 AM5/5/05
to
What would the VOD of a nuclear warhead be? Surely it has been measured.


Me

unread,
May 5, 2005, 2:58:28 PM5/5/05
to
In article <4279ba8c$0$5181$afc3...@news.optusnet.com.au>,
"Short Fuse" <shor...@mail.com> wrote:

> What would the VOD of a nuclear warhead be? Surely it has been measured.
>
>

Did you google Los Alamos Labs?

Me

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