Aside from electrical safety issues, the case also helps regulate
airflow over components, and prevents objects(spilled drink, paper
clips, etc) from causing damage to the components.
As for starting the pc, the ATX power switch is a 'momentary' action
switch. When you press the switch, it simply shorts the power pins on
the motherboard header for an instant, then releases.
To start the pc without the ATX switch, all you need to do is touch the
power pins on the motherboard header for an instant with a small
screwdriver, which does the same as pressing the power
button...momentarily shorting the pins. :)
That said, if your going to run the pc without the case, a few tips:
place the components on a piece of cardboard;
leave the plastic motherboard stand-offs on the motherboard which will
help prevent it from grounding and allow clearance for expansion card
brackets(they extend below motherboard at edge);
position the pc fans(or other fan) to blow across motherboard especially
to keep the chipset and memory cool;
keep food and drink and other objects away from the exposed components!
Any for safety sake, unplug the PSU when not using the 'exposed' system,
especially if theres young children in the household!!! :eek: