The BIOS can only boot from the RAID, if the
BIOS has a code module for the disk controller hardware.
That is termed a "boot ROM", and it is a code
module stored in the main BIOS chip.
Most motherboards, you press <control> plus another key,
while the system is POSTing, to get to the BIOS RAID screen.
In the BIOS RAID setup screen, you want to verify that the
RAID 10 array has a "Healthy" status and is not "Degraded"
or "Failed". If it is "Failed", it will not boot.
Check the S7025 manual, to determine what key combination
to press early in the BIOS POST process.
In the BIOS, "Interrupt 19 Capture" needs to be enabled.
It is enabled by default, but you should verify that.
The RAID setting doesn't mention a "boot ROM" in the BIOS.
On some motherboards, you enable RAID on Intel Southbridge,
but you also have to enable the "boot ROM" for the RAID.
That gives INT 0x13 (decimal 19) boot support. It appears
on your S7025, setting the Intel SATA ports to RAID, is
sufficient for this.
You should also review the boot order settings, and make sure
the RAID volume (that you verified in the RAID BIOS setup screen),
is also listed as a boot option.
http://www.tyan.com/manuals/S7025_Manual_v1.4.pdf
Paul