Getting out of ideas...
When you say "It was 42 degrees when I went to bed" you mean the box, not the room ambient temperature, right? You don't live in Hell, don't you? :-)
42ºC is not that hot, my box is at that temperature now, with 23ºC of room ambient temperature. That does not explains the box lockup.
Yes it has hanged, as it did not responds to neither to the front nor the back button; the fact that you can see it when you browse the network from other computers is only due to cache effects.
I don't think that it was a bad fw flash, it either works or not. I think that there must exists a hardware problem in the box, probably a memory problem.
You can try several other things:
1-remove the disks and let the box running overnight, to see if it hangs. This will definitively exclude heat as the issue source.
2-run Alt-F from RAM memory instead of flash memory: proceed as if flashing firmware (System->Firmware) but instead of hitting the FlashIt button use the TryIt buton, then Reboot. This can only be done with Alt-F fw. Then let the box run overnight to see if it hangs. This will exclude flash memory as the issue source.
3-Flash the vendor's fw back (clear settings first). This will exclude Alt-F as the issue source. If that solves the issue, please report back, I would like to know.
I don't really think that the issue is Alt-F itself, I have it running on my DNS-323-rev-B1 box by more than four years now.
I think that your box hardware has reached a marginal status, which deploys a hardware malfunction over time.
Luck,
Joao