Hi Umesh,
The values that are defined in the php config file, and that are also in the .net config file are:
User Agent
Developer Token
Client Customer Id
OAuth2 Client Id
OAuth2 Client Secret
OAuth2 Refresh Token
The only difference is that the .net config file specifies that the Oauth mode is "application." Do I need different OAuth2 credentials for each application? Or should everything be working correctly with all of the settings being copied over?