Hi Lim,
To be honest, ADVISOR was designed to be very easy to use for people who want to just choose a pre-existing vehicle model and adjust it slightly and hit "run" and see the results. However, your objective goes far beyond the originally use case. Because of that, you're going to have to put in the work to learn Matlab, learn Simulink, and learn how ADVISOR works and that is a fairly large commitment. You can, of course, read all of the ADVISOR documentation in the documentation folder and look at some of the excellent technical reports on ADVISOR (search "ADVISOR vehicle" on the NREL publications site). Just realize that if you really want to get ADVISOR to do a decent job of predicting the energy usage of a bicycle, you're going to have to forge a lot of new ground on your own.
You might want to reassess what your goals are and whether you want to spend your time extensively modifying ADVISOR or whether you want to just learn the physics about simulating bicycles for energy use. There is another tool from NREL called FastSIM which is a vehicle model written in Microsoft EXCEL. If you're brand new to programming and simulation in general, that freely available spreadsheet might be easier to download and modify to get the basic physics of motion and adapt to a bicycle than ADVISOR. You also might just want to check out a vehicle dynamics book and learn to code your own solution in something like Matlab or Python without all of the complexity of ADVISOR. Just some thoughts for you to consider.
Michael