Passingby,
They are all there inside tiddlywiki to be discovered. However I do wish we had it better documented. Some are defined in themes and pallets. If you look at the page and tiddler (view edit) templates you can find what is applied in common situations then use advanced search to find the class definition. All very fiddly.
I think you can also use the browsers developer tools, inspect to discover what class is applied to what.
Control Panel > Info > Advanced > Stylesheets also points you to the stylesheets in use and somewhat critically their order, should one override the other.
Remember unless you want a global change, it is best to override a value where you need it not globally. <style>css here<style> works in tiddlers (when I last tried).
Regards
Tony