First and foremost, those are some very rare, and very pretty, Campy MTB cranks, and they deserve to be on a unique and neato bike.
Second, count me among those who can, or thinks he can, which are the same thing out here in Subjectiveland where we all ride, feel the differences between 170, 172.5, and 175. (I haven't turned a set of 165s since I raced the track as a junior... back before Presidential candidates went on late-night TV... and sat in with the band.) I find that I prefer 170s for a sporting road bike. All my MTBs have had 175s, so I don't actually know if that's right or not.
Still, the differences are small. I'd expect the longer cranks to be at their best in a 1x gravel/ATB-type situation, but I doubt I'd hate 'em on a road bike, especially a loaded one. And, like I said, they're too gorgeous not to be on a bike. Just be careful. That Century finish, as beautiful as it is, is really fragile. Why Campy ever put it on mountain bike parts I'll never know, but I'm guessing it involved lots of wine and gesticulation. I had a buddy back in the mid-Naughties who had Century C-Record on a JB-painted Ti Holland. The finish still looked great, and Randor rode the tears outta that bike, but he also took care of it the way I tell myself that I would but know I wouldn't.
--Shannon