Firefox shipped it in version 48 [2].
This is a trivial change [3] and the performance impact should be minimal if any. (I'm fast-tracking this to ship because it's so trivial that implementing it behind a flag seems to be an overkill.)
Owner: js...@chromium.org
Chromestatus: Not created. Will make one if necessary.
[1] http://www.ecma-international.org/ecma-402/3.0/#sec-intl.getcanonicallocales