I do not think Windows has that much power to stop you, as an
individual user, from changing your own preference. You certain may
not be able to change the default web browser of the whole system
(that does require the IT people), but I think it should be entirely
okay to change it only in your own account. To verify that, I just
logged into our Windows server, where I do not have admin rights, and
I was able to do that in Chrome.