Hi Giuseppe,
If I'm guessing this correctly, you want to use the coupling Liouvillian from Garden/Zoller's formalism for cascaded quantum systems, where you want to take the output of the cavity and feed-forward it into the atom?
[CAVITY] ----c1----> [ATOM] --------> c3
--
--
--
c2 <--
Then you need:
c1 = sqrt(kappa * (1 - eta)) * a
c2 = sqrt(kappa * eta) * a + sqrt(gamma/2) * sm
c3 = sqrt(gamma/2) * sm
c_ops = [c1, c2, c3]
and
H1 = 1 / (2 * 1j) * (kappa * gamma * eta) * (a * sm.dag() - a.dag() * sm)
Which is then in a form that you can easily put into mcsolve. My understanding is that as long as its a Lindblad term, you can always make some sort of decomposition like this, where you have a collapse operator that can represent continuous measurement. (Though it's not always super obvious to arrive at that.) An example that uses a slightly more complicated version of this form is
Phys. Rev. Lett. 78, 3221 (1997).
Hope this is what you're look for!
Kevin