I don't think this would make sense as a hint since most often on a tab there is only one video playing.
For websites that youtube-dl supports (assuming you have the latest mpv), you can just add a mapping like this:
nmap -ex <leader>y execute "silent !mpv '" + buffer.URL + "' &"
For other websites, I've been using a script that fakes clicks and mouse movement to open firebug, click on a video to pause/play it, copy the direct link, and then pass that url to mpv. This is pretty hideous, but it works on 99% of sites I've tried. I just found the media sniffer plugin which would be easier to use since it automatically puts the direct link in the right click menu. So that's one way to do it. Do you have any js experience? It would be much nicer to get the direct link with js from firebug or media sniffer or some other way and just make a command instead of faking mouse movement. I'll see if I can figure out a way to do that..