Optimize css delivery means you have to determine what css is necessary to display the upper portion of your page and inline that in the page. The rest is loaded after the page finishes loading via a script. The inlined css is called the "critical css required to render the page". That css will possibly differ from page to page, which makes it difficult to do an entire site. You'd have to figure out what critical css can be used for multiple pages.
Even for advanced users, this is a lot of work and probably should be done last. Feel free to play with it on a test page, but otherwise I would ignore that for now.