To upgrade an existing MongoDB deployment to 3.0, you must be running 2.6. If you’re running a version of MongoDB before 2.6, you must upgrade to 2.6 before upgrading to 3.0. See Upgrade MongoDB to 2.6 for the procedure to upgrade from 2.4 to 2.6. Once upgraded to MongoDB 2.6, you cannot downgrade to any version earlier than MongoDB 2.4.
http://docs.mongodb.org/manual/release-notes/3.0-upgrade/#upgrade-requirements