Hello George,
I figured it out by doing the following way for adding multiple key/values in Metadata.
/// META-DATA
$googleMetadataItemsObj = new Google_Service_Compute_MetadataItems();
$googleMetadataItemsObj=array(array("key"=>'firstkey',"value"=>'firstvalue'),array("key"=>'secondkey',"value"=>'secondvalue'));
$googleMetadataObj = new Google_Service_Compute_Metadata();
$googleMetadataObj->setKind('compute#metadata');
$googleMetadataObj->setItems($googleMetadataItemsObj);
/// META-DATA