You can't access a user's friend list. Only a Facebook application can.
So the first step is to create a Facebook application.
Then, you can use the login dialog plugin and set your application ID in it.
When a user hit the button, it asks him to accept that your FB application can get his/her infos & friends list.
Lucky you, the friends list is part of the main scope, so you don't have to ask anything more.
Since latest API releases, friends list is force scoped to mutual friends using the app too (before that, you could list the entire list of user's friend...).
Sadly, this friends list will only gives you the full list of user's friends, as an array of objects (id, name, first_name, last_name, gender). Yup, that means if a friend signed-in not via Facebook login but a regular form, you're doomed...
Remi