I use Kontakt samples in the Extempore sampler as well.
In case you wanted a few more details, here's the process:
1. find the sample audio files (directories of wav files in your NI
sample directory, wherever that might be)
2. figure out which files map to which pitches (usually this will be
encoded in the filename somehow, although there's usually no
consistency, even between different Kontakt sample libs)
3. create an extempore sampler instrument
4. load the samples into your new sampler instrument
(examples/external/sampler.xtm has some example code for this)
5. ???
6. profit!
Cheers
Ben