Session key is the session 's primary key. Not the session itself.
What you want to assign to your field is a session, not its key. So use request.session.
However.
Please very careful when using FK' s to sessions, sessions are meant to be short lived, and could / should be deleted once they expire (ie. When the user logs off or after a specific duration), depending on your backend.
I'm not sure what you're trying to achieve, but I think that FKing to sessions is, at the very list, pretty risky.
Especially given that the default on delete behavior of a ForeignKey is cascade.
I'm sorry, I have some trouble understanding exactly what you need, could you please try and provide a bit more context ? :-)
My mistake then, sorry about that!