Hi Terence,
That's great that you're interested in AppScale. Most people that use AppScale use the default App Engine APIs that it provides.
If you plan on using AppScale's default datastore, you won't need a Go driver for Cassandra. The datastore is an abstraction layer written in Python that will interact with Cassandra for you. Google's App Engine documentation describes how to use the datastore api:
https://cloud.google.com/appengine/docs/go/datastore/creating-entities.
If you need your Go application to interact with Cassandra directly, then you will need either a driver or some library that uses Cassandra's thrift interface. That would be an unusual use case though, and it would be a departure from the App Engine model.
Let me know if you have any other questions.
-Chris