There are some info regarding that on the manual page, that I don't know if it applies to your use case:
follow symlinks (S)
This parameter allows the Samba administrator to stop smbd(8) from following
symbolic links in a particular share. Setting this parameter to no prevents any
file or directory that is a symbolic link from being followed (the user will
get an error). This option is very useful to stop users from adding a symbolic
link to /etc/passwd in their home directory for instance. However it will slow
filename lookups down slightly.
This option is enabled (i.e. smbd will follow symbolic links) by default.
Default: follow symlinks = yes
...
allow insecure wide links (G)
In normal operation the option wide links which allows the server to follow
symlinks outside of a share path is automatically disabled when unix extensions
are enabled on a Samba server. This is done for security purposes to prevent
UNIX clients creating symlinks to areas of the server file system that the
administrator does not wish to export.
Setting allow insecure wide links to true disables the link between these two
parameters, removing this protection and allowing a site to configure the
server to follow symlinks (by setting wide links to "true") even when unix
extensions is turned on.
If is not recommended to enable this option unless you fully understand the
implications of allowing the server to follow symbolic links created by UNIX
clients. For most normal Samba configurations this would be considered a
security hole and setting this parameter is not recommended.
This option was added at the request of sites who had deliberately set Samba up
in this way and needed to continue supporting this functionality without having
to patch the Samba code.
Default: allow insecure wide links = no
and several questions regarding following or not following
symlinks.
When you hit Submit in the samba webUI, the running samba is notified that its configuration file has changed using 'rcsmb reload' (in the log: Reloading services after SIGHUP), but if the server sees no changes, probably it will do nothing.
If you want the webUI to not follow symlinks, look at line 144 in /usr/www/cgi-bin/smb.cgi