Try exiting the browser, and then restarting.
The first attempted load from a page supporting SDCH should include the get-dictionary header.
To see if you've "missed" the load (already), visit:
about:histograms/Dictionary
You'll see (after you've loaded at least one dictionary) a histogram of the sizes of dictionaries loaded. The page will look something like:
Histogram: Sdch3.Dictionary size loaded recorded 1 samples, average = 96018.0 (flags = 0x1)
0 ...
83848 ------------------------------------------------------------------------O (1 = 100.0%) {0.0%}
110434 ...
The above shows I've loaded one dictionary (1 sample), and the average size was 96K. This sample appears in the histogram bucket with the range form 83484 to 110434.
Hope that helps,
Jim