If that is the case, that means the Application context isn't working on your device.
What you can do is try other apps. Add a few more apps to the profile, run each app to see if the profile triggers at all. This is to test whether the Application context works on your phone.
If the Application context doesn't work on your phone, there are still a few alternatives. For example, App Changed context, Variable Set %WIN context, and Logcat context. If you have AutoInput Plug-in, there is also another context you can use.