The Lie Algebra module only seems to handle the A-G groups. Wouldn't it be prudent to add on SO(3), SU(2), U(1), stuff that tends to be used by physicists/representation theorists more often? I'm checking out the physics module, too, but so far haven't found anything.
Also take into account that we already have a differential geometry module (sympy.diffgeom).
Lie Groups are manifolds in differential geometry with the addition of the Lie bracket operations, while Lie algebras are their tangent space.
The differential geometry module already supports differentiable manifold nicely. One point could be to extend it. There was even one paper once about how to represent a Lie group differentiable manifold in a CAS.
Connection from point 3 to points 1,2 could be handled by simple replacement/substitution operations.
As a side note, that might be a good first step toward contributing, seeing if you can do something with representation theory here. Of course, I've got to brush up on that, before I even consider it, having been away from physics for a while...