Generally, while using rbenv, you can set the global ruby version you want to use through
rbenv global [2.4.1]
But that would set the ruby version for whenever a local version is not set. When you invoke
rbenv local [2.4.1]
you set a specific version for the project you are working in (actually it simply creates a .ruby-version file with the version number in it.
My guess would be that Rubymine would also pick that up (I don't have ruby mine), as I can only expect it to open up an environment that is based on your other settings, but this is something you might want to verify though.