To get this working in dom0 install some software:
sudo qubes-dom0-update pulseaudio-utils
sudo qubes-dom0-update xbacklight
Then add the following lines to .config/i3
# Pulse Audio controls
bindsym XF86AudioRaiseVolume exec --no-startup-id pactl set-sink-volume 1 +5% #increase sound volume
bindsym XF86AudioLowerVolume exec --no-startup-id pactl set-sink-volume 1 -5% #decrease sound volume
bindsym XF86AudioMute exec --no-startup-id pactl set-sink-mute 1 toggle # mute sound
# Sreen brightness controls
bindsym XF86MonBrightnessUp exec xbacklight -inc 20 # increase screen brightness
bindsym XF86MonBrightnessDown exec xbacklight -dec 20 # decrease screen brightness
that's it,
Jon