Predicting CLmax is very complex and is beyond the theory of pure potential flow methods (which VSPAERO is one).
Consequently, without additional models, VSPAERO will predict flow that does not separate and you will see unreasonable values at unreasonably high alpha.
VSPAERO has two other models that can be applied.
1) a 2D CLmax can be applied. To use this, look up your airfoil in Theory of Wing Sections or a similar reference, look up the 2D CLmax at an appropriate Reynolds number, and put that value into the VSPAERO GUI.
2) an empirical Cp limit can be applied. To use this, choose the Carlson Pressure Correlation, but then also set the Mach number and Reynolds number for your model appropriately. The default Mach=0 will not work with this model.
RC Aircraft operate at very low Reynolds number -- many of the data sets might not extend down to such low Re. However, XFoil is pretty well suited to low Re flow, you can always set up and run some 2D analyses there yourself. If you are using the 2D CLmax approach, VSPAERO does not allow you to put in multiple airfoils worth of data -- if you choose the lowest CLmax, you will obtain a conservative result for CLmax, but you will want to think about what this means for tip stall if you have a root and tip with dramatically different CLmax values.
Rob