Be extra careful about ESD/surge events; the automotive electrical environment is quite nasty, especially in older vehicles that have mechanical voltage regulators.
Depending upon where you tap the power & ground, your circuit can be affected by large di/dt events, such as starting, charging, A/C compressor cycling.
A volt-sensor is probably just a resistor-divider to shift the voltage down to a level that can be safely read from a GPIO pin; probably not a full-on A/D converter.
If the resistor values are in the 100K range, or higher, you wont have to worry about ESD or reverse polarity.