Dear vishwanath,
The welding procedure is qualified for base metal thickness (affecting cooling rates),and weld metal thickness (heat input ).
Whatever WPS opted for making a groove weld joint shall be qualified for the given base metal thickness range. whereas weld metal deposit qualification only restricts for upper limit and there is no lower limit ie zero also.
by seeing this only PQR 3 is applicable, However GTAW is excluded in that.Since none of your PQR qualified using GTAW for the given thickness range. You need to qualify a WPS so as to meet your requirements both for bm thickness and required weld metal thickness. Refer QW 200.4.