I have some previous experience with Postilion so here is my take on it.
The flow is usually
external network ->source node -> Postilion Transaction Manager -> Sink Node -> Host/external network.
Postilion will have their Source and Sink Nodes to talk to major networks and hosts which you would have to purchase.
Now if you need to talk to Postilion, they have a Source/Sink Node called PostBridge which you would talk to. Use their source node if you need to send requests , use their sink node if you want to receive requests rom them.
You would write something in JPOS that talks to PostBridge ,and it's pretty simple, you use the NACChannel (2 byte length header) and the postpack xml packager (that will understand the Postbridge ISO8583) that will unpack and pack the messages.
Source node would get Requests and translate it to an internal Position ISO8583 and send it to their Transaction Manager. Based on routing config in Postilion the transaction manager updates and forwards Postilion ISO8583 to the sink Node. Sink Node translates this ISO8583 to the external network format.
Transaction matching within the system is done using 127.2 what they call a switch key.
-chhil