Hi Jairo,
1. It might be possible, but I believe it might be limited by GRASS
2.
The number of threads used can be changed by setting the environment variable OMP_NUM_THREAD. But I do not know if it impacts individual instances, or if it is global.
3. Only if you try to write to the same file in parallel, I believe. You might try the GRASS mailing list for that answer.
However, running all your ensemble members in series might not be necessarily slower than running them in parallel (and you avoid some potential headaches). Itzï will use all available threads anyway. I never checked how it scales to that number of cores, but it might be interesting to test.
Cheers,
Laurent