The ocean surface and the atmosphere are in a near-equilibrium condition--the pH of the ocean and the CO2 concentration of the air are closely coupled. The consequence is that the ocean is getting more acidic with rising atmospheric CO2. If we raise the pH of the ocean surface, the atmospheric CO2 problem goes away.
Interesting fact (recognized by many): More than 99.9% of the earth is basic. Only 0..1% or less is acidic and needs neutralization (the biosphere). Can't we find a manageable way to apply enough base to the problem? (I imagine it should take dispersal of about 1000
cu.km of ultramafics to do the job, but I am an optimist.)