it's really too general a question for me to answer in a short amount of time.
If you're a beginner I'd suggest you download and study some of the sample files on the PST website - see here -
http://www.pstnet.com/support/samples.asp - run them through, see what they do and then look at the source code to see how it's done.
to get you started, for your varying correct responses, you probably want a column in your TrialList to store your correct response - eg 'corr_resp' and then on the properties dialog for your slide you can put the column name in the correct response field but enclose it in square brackets e.g. [corr_resp]
you just need to populate the triallist table with the appropriate values to correspond with the images that you'l show. Hopefully you can hard code these. If not then you can populate the triallist at runtime but that starts to get tricky for beginners.