Hi,
DSpace stores all content files in the [dspace]/assestore/ folder (in a hierarchy of subfolders), and all metadata is stored in the Database. So, one way to migrate DSpace from one server to another is to
(1) Install DSpace 6.x on the new server,
(2) Copy the [dspace]/assetstore from the old server to the new one (this directory structure is identical in all versions of DSpace)
(3) Delete the (default) empty database on the new server,
(4) Dump the database from the old server (using a tool like pg_dump from PostgreSQL) and recreate it on the new server (using a tool like pg_restore from PostgreSQL)... when Tomcat starts up, it should auto-upgrade this database to being compatible with 6.x,
or you can run `dspace database migrate` from commandline.
(5) Finally, start Tomcat up and see if it works. You then may need to recustomize the User Interface and/or configurations if necessary.
Hopefully that helps clarify. Let us know on this list if you have further questions.
Tim