There's many flavors for 3D analysis but none are free. There's standalone heat transfer or multiphysics platforms that have heat transfer solvers. Many are quite pricey $3,000 or more.
There's only one standalone heat transfer software that I know will do 3D radiosity based grey radiation. Others are fixed heat transfer coefficients. If you need grey radiation (not necessary for most problems) then you need to look at multiphyics platforms that are probably $10k plus.
None are plug and play like Therm so will need experience on finite element modeling, meshing, and general concepts in heat transfer.
I use Trisco/Solido developed by Physibel.
Strand 7 also has heat transfer but is primarily a structural FEA and I use in strain problems.
Then there's Ansys, FEMAP, Comsol, etc. multiphysics platforms which are not streamlined for building physics but surely can be used.