So it is ...
I ran this in THERM 7.7, as we don't really support 7.6 any more. But it showed the same issues.
When running the boundary conditions, the program is putting a red line between polygons, which means there is a very small space between them which the program detects as a void
There is also a space surrounded by polygons that is not a polygon, ie, another void -- you have set the insulation color to white, so it is very hard to see the fact that the white space is not a polygon
It took a few tries, but I was able to delete and redraw the polygons that had small spaces between them, as well as filling the white void with a material. And then I was able to get the file to not have any issues.

You should probably change your snap settings to snap to horizontal and vertical, so that you can draw rectangular polygons with straight sides -- the sides on your original drawing were not straight horizontally or vertically.
I am attaching the file I fixed, but again, it's THERM 7.7, so you won't be able to open it with 7.6.
You might want to update to a more recent version of THERM.