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I’ve never had a use case where this made sense.
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Paint it or not, sub 0.08mm layer heights will help with the surface quality. Spray primer does not fill the steps between 0.10mm layers, but with 0.04mm layers the steps might be completely invisible after painting.
It does not really matter if the print takes 4 hours or 14 hours, I would (almost) always take the better detail and quality.