Sriharsha,
If you have a HC-06 attached to your Arduino UNO, then you
CAN NOT USE the new BLE component. Go to
ai2.appinventor.mit.edu, the production server and use the BluetoothClient, found in the Connectivity category. If you have something else attached to your Arduino UNO, then tell what it is and whether it supoorts BLE.
As a said, there are many examples in the forum on how to use the HC-06 0r HC-05 with App Inventor.
Cheers, Ghica.