Hi Cecily,
I would start with metadata understanding. My experience tells me that you should always manage the most valuable asset for your end users (which most of the time are Librarians and/or other preservation professionals). For how the world moves, XML and XSLT(path, etc) are not enough today. RDF is a must, Linked data and SPARQL also.
Under the same understanding, end users are the most important asset (yeah, it's not really metadata!), Solr knowledge is also a need. From how things work, to what/how stuff is stored in an index. Basically because users do two basic actions: Search + Look. (plus ingesting of course) and if those things don't work you get frustration.
Since Islandora is based on Drupal and Drupal is php, and since learning a new CMS is far less challenging that learning to code a new language, some basic/medium PHP knowledge is also required.
I don't think there are many people out there that manage the whole Stack as per se. Fedora is not that easy to learn without getting your hands onto installing it, which means a mix of hard and soft skills, from basic Unix management, Some services knowledge (Apache 2, Tomcat, Solr already mentioned), installing stuff, etc + being able to learn independently (research), which leads to good communication skills to interact with the community forums. Most people dismiss the importance of reading + failing an retrying . I have learned a lot from just browsing through the code, watching how the different modules interact, changed, evolved in time and even more by making stuff fail.
And finally, internal communication skills. Like being able to ask end users for their needs, helping them to find solutions and transferring those needs to technical actions and back.
Repositories are as complex as the information you wan't to preserve, and i personally think many soft skills lead to better adoption of hard skills, not the other way.
Not a formal definition, but if i where looking for someone, i would put as many efforts as possible to find someone as flexible enough and communicative enough to jump into technical learning that also has some love for preservation.
Cheers
Diego