I was noticing the same issue while developing a mobile version of our outages map. The iPhone and Android devices "helpfully" wrap telephone numbers displayed on a page in code to trigger the dialing function of the phone, but do nothing for telephone numbers that appear in Google Maps Info Windows. A little digging led me to this:
Using mobile-specific HTML, CSS, and JavaScript (Mobile web part 5)http://davidbcalhoun.com/2010/using-mobile-specific-html-css-javascriptIn it, the author describes two additional schemes for hyperlinks,
tel and
sms. An example would be <a href="tel:
18005555555">Call us at
1-800-555-5555</a>
I currently have it working in a simple Info Window (not populated via KML) on both iPhone and Android devices; I suspect the KML could be sufficiently crafted to get it working in its Info Window as well.
JF