Hello Adam,
Yes, calling /fcr:fixity on a Binary resource (aka Non-RDF Source, aka datastream) calculates the fixity of the current version of that resource:
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curl localhost:8080/rest/collection/image/fcr:fixity
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If you wanted to check the fixity of other versions, you would indeed simply call /fcr:fixity on the labelled version of that resource (version label below is 'v0'):
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curl localhost:8080/rest/collection/image/fcr%3aversions/v0/fcr:fixity
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Note, the URL encoding of "fcr:versions" to "fcr%3aversions".
Andrew